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MCQ Questions for Class 11 Chemistry sets 3
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1. Red phosphorus is chemically less reactive because
It does not contain P – P bonds
It dos not contain tetrahedral P4 molecules
It does not catch fire in air even upto 400°C
It has a polymeric structure
2. Which of the following will not produce hydrogen gas?
Reaction between Fe and dil. HCl
Reaction between Zn and NaOH
Reaction between Zn and conc. H2SO4
Electrolysis of NaCl in Nelsons cell
3. The structure of diBorane contains
Four 2c – 2e bonds and two 3c – 2e bonds
Two 2c – 2e bonds and two 3c – 2e bonds
Two 2c – 2e bonds and two 3c – 3e bonds
Four 2c – 2e bonds and four 3c – 2e bonds
4. Which of the following oxidation states are most characteristic for lead and tin respectively?
2, 2
4, 2
2, 4
4, 4
5. Among the C-X bond (where, X = Cl, Br, l) the correct decreasing order of bond energy is
C−I > C−Cl > C−Br
C−I > C−Br > C−Cl
C−Cl > C−Br > C−I
C−Br > C−Cl > C−I
6. In the upper layers of atmosphere ozone is formed:
By action of electric discharge on oxygen molecule
By action of ultraviolet rays on oxygen molecule
By action of infrared rays on oxygen molecule
Due to sudden drops of pressure
7. Oxygen gas can be prepared from solid KMnO4 by
Dissolving the solid in dil. HCl
Dissolving the solid in conc. H2SO4
Treating the solid with H2 gases
Strongly heating the solid
8. Which is not the correct statement for Boron?
It exhibits Allotropy
It exists in both crystalline and Amorphous form
It forms solid chlorides
It forms volatile hydrides.
9. When excess of Kl is added to copper sulphate solution:
Cuprous iodide is formed
l2 is liberated
Potassium iodide is oxidized
All
10. Which of the following statements regarding ozone is not correct?
The oxygen-oxygen bond length in ozone is identical with that of molecular oxygen
The ozone is response hybrid of two structures
The ozone molecule is angular in shape
Ozone is used as a germicide and disinfectant for the purification of air.
11. K2[Hgl4] detect the ion/group
NH2
NO
NH2+
Cl–
12. Which of the following has least covalent P−H bond?
PH+4
P2H+5
P2H2+6
PH3
13. If Cl2 gas is passed in to aqueous solution of Kl containing some CCl4 and the mixture is shaken then:
Upper layer becomes violet
Lower layer becomes violet
Homogenous violet layer is formed
None of these
14. Which of the statement is true for the above sequence of reactions?
Z is hydrogen
X is B2H6
Z and Y are F2 and B2H6 respectively
Z is Potassium Hydroxide
15. Ammonia gas can be dried by
conc H2SO4
P2O5
CaCl2
Quick lime
16. Inert gases such as helium behave like ideal gases over a wide range of temperature .However; they condense into the solid state at very low temperatures. It indicates that at very low temperature there is a
Weak attractive force between the atoms
Weak repulsive force b etween the atoms
Strong attractive force between the atoms
Strong repulsive attractive between the atoms
17. In general, the Boron Trihaides act as
Strong reducing agent
Lewis Acids
Lewis Bases
Dehydrating Agents
18. On heating ozone, its volume.
Increase to 1.5 times
Decreases to half
Remain uncharged
Becomes double
19. In the compound of type ECl3, where E = B, P, As, or Bi, the angle Cl – E – Cl for different E are ion the order:
B > = P = As = Bi
B > P > As > Bi
B < P = As = Bi
B < P < As < Bi
20. If two compounds have the same empirical formula but different molecular formula they must have
Different percentage composition
Different molecular weight
Same viscosity
Same vapour density
21. Identify the chiral molecule among the following:
Isopropyl alcohol
2-pentanol
1-bromo 3-butene
Isobutyl alcohol
22. 0.0833mol of carbohydrate of empirical formula CH2O contain 1g of hydrogen. The molecular formula of the carbohydrate is
C5H10O5
C3H4O3
C12H22O11
C6H12O6
23. The displacement of electrons in a multiple bond in the presence of attacking reagent is called
Inductive effect
Electromeric effect
Resonance
Hyper conjugation.
24. Which of the following cannot be represented by resonance structures?
Dimethyl ether
Nitrate anion
Carboxylate anion
Toluene
25. An organic compound which produces a bluish green coloured flame on heating in presence of copper is
Chlorobenzene
Benzaldehyde
Aniline
Benzoic acid
26. Which one is strongest acid among following options?
CH2FCOOH
CH2ClCOOH
CHCl2COOH
CHF2COOH
27. Insulin contains 3.4% sulphur. The minimum molecular weight of insulin is
350
470
560
940
28. What is the correct IUPAC name of
4-methoxy-2-nitrobenzaldehyde
4-formyl-3-nitro anisole
4-methoxy-6-nitrobenzaldehyde
2-formyl-5-methoxy nitrobenzene
29. 59 g of an amide obtained from a carboxylic acid, RCOOH, liberated 17 g of ammonia upon heating with alkali. The acid is
Formic Acid
Acetic Acid
Benzoic Acid
Propionic Acid
30. In the Dumas method, the nitrogen present in organic compound gets converted to
Sodium Cyanide
Gaseoue Ammonia
Dinitrogen Gas
Ammonium Sulphate
31. 0.0833mol of carbohydrate of empirical formula CH2O contain 1 g of hydrogen. The molecular formula of the carbohydrate is
C5H10O5
C3H4O3
C12H22O11
C6H12O6
32. The compound MCQ Questions for Class 11 Chemistry Chapter 12 Organic Chemistry Some Basic Principles and Techniques with Answers 3 is known by which of the following names
Bicyclo-[2, 2, 2] octane
Bicyclo-[2, 2, 1] octane
Bicyclo-[1, 2, 1] octane
Bicyclo-[1, 1, 1] octane
33. Which one of the following conformations of cyclohexane is chiral?
Twist boat
Rigid
Chair
Boat
34. If 0.228 g of silver salt of dibasic acid gave a residue of 0.162 g of silver on ignition then molecular weight of the acid is
70
80
90
100
35. If there is no rotation of plane polarized light by a compound in a specific solvent, thought to be chiral, it may mean that
The compound may be a racemic mixture
The compound is certainly a chiral
The compound is certainly meso
There is no compound in the solvent.
36. Which element is estimated by Carius method
Carbon
Hydrogen
Halogen
Nitrogen
37. Inductive effect involves
displacement of σ electrons
delocalization of π electrons
delocalization of σ-electrons
displacement of π-electrons
38. A crystalline solid possess which one of the following property?
Irregularity
Non- symmetric
Perfect geometric pattern
non- stability
39. Which of the following behaves both as a nucleophile and as an electrophile?
CH3C ≡ N
CH3OH
CH2 = CHCH3
CH3NH2
40. A dibromo derivative of an alkane reacts with sodium metal to form an alicyclic hydrocarbon. The derivative is ______.
2, 2-dibromobutane
1, 1-dibromopropane
1, 4-dibromobutane
1, 2-dibromoethane
41. The position of double bond in alkenes can be located by
Hydrogenation of oil
Ozonolysis
Photolysis
Hydration
42. Nitrobenzene on reaction with conc. HNO3/H2SO4 at 80 – 100°C forms which one of the following products?
1, 2-Dinitrobenzene
1, 3-Dinitrobenzene
1, 4-Dinitrobenzene
1, 2, 4-Trinitrobenzene
43. Some meta-directing substituents in aromatic substitution are given. Which one is most deactivating?
–C ≡ N
-SO3H
-COOH
-NO2
44. Which of the following compounds will exhibit geometrical isomerism?
1 – Phenyl – 2 – butene
3 – Phenyl – 1 – butene
2 – Phenyl – 1 butene
1, 1 – Diphenyl – propene
45. The order of decreasing reactivity towards an electrophilic reagent, for the following : (i) Benzene (ii) Toluene (iii) Chlorobenzene (iv) Phenol would be:
(i) > (ii) > (iii) > (iv)
(ii) > (iv) > (i) > (iii)
(iv) > (iii) > (ii) > (i)
(iv) > (ii) > (i) > (iii)
46. Pure methane can be prepared by
Soda lime decarboxylation
Kolbes electrolytic method
Wurtz reaction
Reduction with H2
47. Hydrocarbon containing following bond is most reactive
C ≡ C
C = C
C-C
All of these
48. The compound C3H4 has a triple bond, which is indicated by its reaction with
Bromine water
Bayers reagent
Fehling solution
Ammonical silver nitrate
49. The angle strain in cyclobutane is
24°44
29°16
19°22
9°44
50. The first fraction obtained during the fractionation of petroleum is:
Gasoline
Diesel Oil
Hydrocarbon Gases
Kerosene Oil
51. 2 – Phenylpropene on acidic hydration gives
2 – Phenyl – 2 – propanol
2 – Phenyl – 1 – propanol
3 – Phenyl – 1 – propanol
1 – Phenyl – 2 – propanol
52. The coal tar fraction which contains phenol is:
Heavy Oil
Light Oil
Middle Oil
Green Oil
53. Which one of these is not true for benzene?
There are three carbon-carbon single bonds and three carbon-carbon double bonds.
Heat of hydrogenation of benzene is less than the theoretical value
It forms only one type of mono substituted product
The bond angle between carbon-carbon bonds is 120 Degree
54. The catalyst used in Friedel – Crafts reaction is
Aluminium Chloride
Anhydrous Aluminium Chloride
Ferric Chloride
Copper
55. Alkyl halides react with dialkyl copper reagents to give?
Alkanes
Alkenes
Hydrogen
Carbon
56. The lowest alkene, that is capable of exhibiting geometrical isomerism is
Ethene
But – 1- ene
But – 2 – ene
Propane
57. Presence of a nitro group in a benzene ring
Activates the ring towards electrophilic substitution
Renders the ring basic
Deactivates the ring towards nucleophilic substitution
Deactivates the ring towards electrophilic substitution
58. The agricultural field that produces maximum methane gas into atmosphere is
Wheat field
Paddy field
Cotton field
Groundnut field
59. Fluorosis, the bone disease, is caused by the presence of
Pesticides in water
Fluorides in water
Carbon monoxide in air
Sulphur dioxide in air
60. The most harmful air pollutant produced by automobiles is
HNO3
NO
SO2
CO
61. Which of the following is responsible for depletion of ozone layer in the upper strata of the atmosphere?
Polyhalogens
Ferrocene
Fullerencs
Freons
62. Which of the following acts as a sink for CO?
Plants
Haemoglobin
Microorganisms present in the soil
Oceans
63. Which is most harmful for life on globe?
Deforestation
Soil Erosion
Increasing Desert
Nuclear Fallout.
64. One of the following is the chief source of water and soil pollution
Agro industry
Mining
Thermal power stations
All of these
65. What is the indicator of pollution in water?
Amount of oxygen
Amount of hydrogen
Amount of BOD
Amount of nitrogen
66. The false statement among the followings:
The average residence time of NO is one month.
Limestone acts as a sink for SOx.
SOx can be removed from flue gases by passing through a solution of citrate ions
Ammonia acts as a sink for NOx.
67. A disease caused by eating fish contaminated by industrial waste, containing mercury compounds, is called as
Minamata disease
Brights disease
Hashimotos disease
Osteosclerosis
68. Identify the wrong statement in the following:
Acid rain is mostly because of oxides of nitrogen and sulphur
Chlorofluorocarbons are responsible for ozone layer depltion
Greenhouse effect is responsible for global warming
Ozone layer does not permit infrared radiation from the sun to reach the earth.
69. Synthesis of ethanal commercially from which of the following reagent is the part of green chemistry?
CH3CH2OH
CH2 = CH2
HC ≡ CH
All of these
70. Which of the following is produced by a reaction of ultraviolet light?
CO2
SO2
O3
NO3
71. Why certain parts of water bodies contain more number of algae?
Due to favorable environment
Due to run-off excess fertilizers
Due to lack of fertilizers
Due to water pollution
72. The substance which is a primary pollutant?
H2SO4
CO
PAN
Aldehydes
73. The volume of 2.8 g of carbon monoxide at 27°C and 0.0821 atm is
30 L
3 L
0.3 L
1.5 L
74. In van der Waal equation of state of gas laws, the constant b is a measure of
Intermolecular collisions per unit volume
Intermolecular attraction
Volume occupied by the molecules
Intermolecular repulsions
75. Which of the following statement is wrong for gases?
Gases do not have definite shape and volume
Volume of the gas is equal to the volume of the container confining the gas
Confined gas exert uniform pressure on the wall of the container in all directions
Mass of the gas cannot be determined by weighing a container in which it is contained
76. The critical volumes of four gases A, B, C, D are respectively 0.025 L, 0.312 L, 0.245 L, 0.432 L, the gas with highest value of van der Wall constant b is
A
B
C
D
77. The value of universal gas constant R depends on
Temperature of Gas
Volume of Gas
Number of Moles of Gas
Units of Volume,Temperature and Pressure
78. A gas deviates from ideal behavior at a high pressure because its molecules:
Attract one another
Show the Tyndall Effect
Have kinetic energy
Are bound by covalent bonds
79. The state of matter that shows the uniformity of behavior :
Solid Liquid
Liquid
Gas
None of the above
80. If 20cm³ gas at 1 atm. is expanded to 50 cm³ at constant T, then what is the final pressure
20 × 150
50 × 120
1 × 120 × 50
None of these
81. How many of the know elements exist as gases at 25°C?
9
11
12
15
82. The states of matter having no definite shape but definite volume:
Gas
Liquid
Solid
None of the above
83. The rise or fall of a liquid within a tube of small bore is called:
Surface Tension
Capillary Action
Viscosity
Formation of Curvature
84. The theory which explains that gases consist of molecules, which are in rapid option is known as
Daltons Atomic Theory
Bohrs Theory
Rutherfords Atomic Theory
Kinetic Molecular Theory
85. Falling drop of water is spherical due to:
Hydrogen Bonding
Surface Tension
Capillary Action
Vlscosity
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